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DOE OSTI · 1199979

Materials Data on RbP(HO)2 by Materials Project

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Abstract

RbP(HO)2 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Rb1+ is bonded in a 6-coordinate geometry to six equivalent O2- atoms. There are a spread of Rb–O bond distances ranging from 2.91–3.11 Å. P5+ is bonded in a distorted tetrahedral geometry to two H1- and two equivalent O2- atoms. Both P–H bond lengths are 1.43 Å. Both P–O bond lengths are 1.52 Å. There are two inequivalent H1- sites. In the first H1- site, H1- is bonded in a single-bond geometry to one P5+ atom. In the second H1- site, H1- is bonded in a single-bond geometry to one P5+ atom. O2- is bonded in a distorted single-bond geometry to three equivalent Rb1+ and one P5+ atom.

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36 MATERIALS SCIENCEcrystal structureH-O-P-RbRbP(HO)2

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2020-07-15. Materials Data on RbP(HO)2 by Materials Project. https://doi.org/10.17188/1199979

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