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DOE OSTI · 1202606

Materials Data on Pb(ClO3)2 by Materials Project

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Abstract

Pb(O3Cl)2 crystallizes in the orthorhombic Fdd2 space group. The structure is three-dimensional. Pb is bonded in a 8-coordinate geometry to eight O atoms. There are a spread of Pb–O bond distances ranging from 2.62–2.77 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted single-bond geometry to one Pb and one Cl atom. The O–Cl bond length is 1.48 Å. In the second O site, O is bonded in a distorted bent 120 degrees geometry to one Pb and one Cl atom. The O–Cl bond length is 1.52 Å. In the third O site, O is bonded in a distorted single-bond geometry to two equivalent Pb and one Cl atom. The O–Cl bond length is 1.54 Å. Cl is bonded in a trigonal non-coplanar geometry to three O atoms.

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36 MATERIALS SCIENCECl-O-Pbcrystal structurePb(ClO3)2

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2020-07-18. Materials Data on Pb(ClO3)2 by Materials Project. https://doi.org/10.17188/1202606

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36 MATERIALS SCIENCE↗