Materials Data on TlSbF4 by Materials Project

Abstract

TlSbF4 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. Tl1+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Tl–F bond distances ranging from 2.71–3.14 Å. Sb3+ is bonded in a 5-coordinate geometry to five F1- atoms. There are a spread of Sb–F bond distances ranging from 2.00–2.58 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a 3-coordinate geometry to one Tl1+ and two equivalent Sb3+ atoms. In the second F1- site, F1- is bonded in a 1-coordinate geometry to three equivalent Tl1+ and one Sb3+ atom. In the third F1- site, F1- is bonded in a distorted single-bond geometry to one Tl1+ and one Sb3+ atom. In the fourth F1- site, F1- is bonded in a distorted single-bond geometry to one Tl1+ and one Sb3+ atom.