Materials Data on Ga17Rh10 by Materials Project

Abstract

Rh10Ga17 crystallizes in the tetragonal P-4c2 space group. The structure is three-dimensional. there are eleven inequivalent Rh sites. In the first Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.45–2.91 Å. In the second Rh site, Rh is bonded in a 6-coordinate geometry to six Ga atoms. There are four shorter (2.46 Å) and two longer (2.73 Å) Rh–Ga bond lengths. In the third Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are four shorter (2.56 Å) and four longer (2.64 Å) Rh–Ga bond lengths. In the fourth Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.45–2.99 Å. In the fifth Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.55–2.66 Å. In the sixth Rh site, Rh is bonded in a 6-coordinate geometry to six Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.45–2.73 Å. In the seventh Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.49–2.75 Å. In the eighth Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.46–2.85 Å. In the ninth Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.48–2.79 Å. In the tenth Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.53–2.68 Å. In the eleventh Rh site, Rh is bonded in a 8-coordinate geometry to eight Ga atoms. There are a spread of Rh–Ga bond distances ranging from 2.51–2.71 Å. There are nine inequivalent Ga sites. In the first Ga site, Ga is bonded in a 2-coordinate geometry to five Rh atoms. In the second Ga site, Ga is bonded in a 4-coordinate geometry to four Rh atoms. In the third Ga site, Ga is bonded in a 4-coordinate geometry to four Rh atoms. In the fourth Ga site, Ga is bonded in a 4-coordinate geometry to five Rh atoms. In the fifth Ga site, Ga is bonded in a 4-coordinate geometry to four Rh atoms. In the sixth Ga site, Ga is bonded in a 2-coordinate geometry to five Rh atoms. In the seventh Ga site, Ga is bonded in a 2-coordinate geometry to five Rh atoms. In the eighth Ga site, Ga is bonded in a 4-coordinate geometry to four Rh atoms. In the ninth Ga site, Ga is bonded in a 2-coordinate geometry to five Rh atoms.