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DOE OSTI · 1205141

Materials Data on CdSiAs2 by Materials Project

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Abstract

CdSiAs2 is Chalcopyrite structured and crystallizes in the tetragonal I-42d space group. The structure is three-dimensional. Cd2+ is bonded to four equivalent As3- atoms to form CdAs4 tetrahedra that share corners with four equivalent CdAs4 tetrahedra and corners with eight equivalent SiAs4 tetrahedra. All Cd–As bond lengths are 2.68 Å. Si4+ is bonded to four equivalent As3- atoms to form SiAs4 tetrahedra that share corners with four equivalent SiAs4 tetrahedra and corners with eight equivalent CdAs4 tetrahedra. All Si–As bond lengths are 2.40 Å. As3- is bonded to two equivalent Cd2+ and two equivalent Si4+ atoms to form corner-sharing AsCd2Si2 tetrahedra.

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36 MATERIALS SCIENCEAs-Cd-SiCdSiAs2crystal structure

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2020-07-15. Materials Data on CdSiAs2 by Materials Project. https://doi.org/10.17188/1205141

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