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DOE OSTI · 1205278

Materials Data on HgClO3 by Materials Project

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Abstract

HgO3Cl crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight HgO3Cl clusters. Hg is bonded in a distorted single-bond geometry to one O atom. The Hg–O bond length is 2.25 Å. There are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.49 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.48 Å. In the third O site, O is bonded in a water-like geometry to one Hg and one Cl atom. The O–Cl bond length is 1.59 Å. Cl is bonded in a trigonal non-coplanar geometry to three O atoms.

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36 MATERIALS SCIENCECl-Hg-Ocrystal structureHgClO3

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2020-07-14. Materials Data on HgClO3 by Materials Project. https://doi.org/10.17188/1205278

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36 MATERIALS SCIENCE↗