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DOE OSTI · 1206417

Materials Data on CeSi2Pt by Materials Project

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Abstract

CePtSi2 crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Ce3+ is bonded in a 10-coordinate geometry to ten Si4- atoms. There are a spread of Ce–Si bond distances ranging from 3.14–3.25 Å. Pt5+ is bonded in a 5-coordinate geometry to five Si4- atoms. There are a spread of Pt–Si bond distances ranging from 2.41–2.44 Å. There are two inequivalent Si4- sites. In the first Si4- site, Si4- is bonded in a distorted single-bond geometry to six equivalent Ce3+, one Pt5+, and two equivalent Si4- atoms. Both Si–Si bond lengths are 2.41 Å. In the second Si4- site, Si4- is bonded in a 4-coordinate geometry to four equivalent Ce3+ and four equivalent Pt5+ atoms.

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36 MATERIALS SCIENCECe-Pt-SiCeSi2Ptcrystal structure

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2020-07-14. Materials Data on CeSi2Pt by Materials Project. https://doi.org/10.17188/1206417

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