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DOE OSTI · 1208399

Materials Data on K(OsO3)2 by Materials Project

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Abstract

KOs2O6 crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. K1+ is bonded to six equivalent O2- atoms to form KO6 octahedra that share corners with twelve equivalent OsO6 octahedra. The corner-sharing octahedral tilt angles are 70°. All K–O bond lengths are 3.16 Å. Os+5.50+ is bonded to six equivalent O2- atoms to form OsO6 octahedra that share corners with six equivalent KO6 octahedra and corners with six equivalent OsO6 octahedra. The corner-sharing octahedra tilt angles range from 41–70°. All Os–O bond lengths are 1.93 Å. O2- is bonded in a distorted bent 150 degrees geometry to one K1+ and two equivalent Os+5.50+ atoms.

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36 MATERIALS SCIENCEcrystal structureK(OsO3)2K-O-Os

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2020-07-16. Materials Data on K(OsO3)2 by Materials Project. https://doi.org/10.17188/1208399

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