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DOE OSTI · 1227137

Research Performance Progress Report

Theopold, Klaus H.
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Abstract

The focus of this project was catalysis by ‘proton coupled electron transfer’ (PCET) to metal bound fragments derived from the most abundant small molecules (i. e. O 2 and N 2 ). There are many important chemical challenges that are tied to this fundamental reaction type. Among these are: metal catalyzed oxidations of organic molecules utilizing O 2 as the oxidant; reduction of O 2 to water close to the thermodynamic potential – in other words, the cathode of any fuel cell based on reactions with O 2 ; transfer of reduced nitrogen species to organic substrates; fixation of nitrogen at modest temperatures and pressures. Any one of these problems has obvious implications for the generation and/or utilization of energy on a large scale.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYCatalysisPCETsmall molecule activation

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Theopold, Klaus H.. 2015-11-30. Research Performance Progress Report. https://doi.org/10.2172/1227137

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