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DOE OSTI · 1263605

Materials Data on Zn(SbO2)2 by Materials Project

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Abstract

Zn(SbO2)2 crystallizes in the tetragonal P4_2/mbc space group. The structure is three-dimensional. Zn2+ is bonded to six O2- atoms to form edge-sharing ZnO6 octahedra. There are four shorter (2.10 Å) and two longer (2.22 Å) Zn–O bond lengths. Sb3+ is bonded in a 3-coordinate geometry to three O2- atoms. There are one shorter (1.97 Å) and two longer (2.03 Å) Sb–O bond lengths. There are two inequivalent O2- sites. In the first O2- site, O2- is bonded in a trigonal planar geometry to one Zn2+ and two equivalent Sb3+ atoms. In the second O2- site, O2- is bonded in a trigonal non-coplanar geometry to two equivalent Zn2+ and one Sb3+ atom.

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36 MATERIALS SCIENCEcrystal structureO-Sb-ZnZn(SbO2)2

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2020-07-15. Materials Data on Zn(SbO2)2 by Materials Project. https://doi.org/10.17188/1263605

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