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DOE OSTI · 1266763

Materials Data on Zn3Co2(CN)12 by Materials Project

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Abstract

Co2Zn3(CN)12 crystallizes in the trigonal R-3c space group. The structure is three-dimensional. Co2+ is bonded in an octahedral geometry to six C+2.17+ atoms. All Co–C bond lengths are 1.87 Å. Zn2+ is bonded in a tetrahedral geometry to four N3- atoms. There is two shorter (1.96 Å) and two longer (1.98 Å) Zn–N bond length. There are two inequivalent C+2.17+ sites. In the first C+2.17+ site, C+2.17+ is bonded in a linear geometry to one Co2+ and one N3- atom. The C–N bond length is 1.17 Å. In the second C+2.17+ site, C+2.17+ is bonded in a linear geometry to one Co2+ and one N3- atom. The C–N bond length is 1.17 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a linear geometry to one Zn2+ and one C+2.17+ atom. In the second N3- site, N3- is bonded in a distorted linear geometry to one Zn2+ and one C+2.17+ atom.

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36 MATERIALS SCIENCEC-Co-N-Zncrystal structureZn3Co2(CN)12

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2020-07-15. Materials Data on Zn3Co2(CN)12 by Materials Project. https://doi.org/10.17188/1266763

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36 MATERIALS SCIENCE↗