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DOE OSTI · 1270793

Materials Data on SbP(Cl2F3)2 by Materials Project

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Abstract

SbF6PCl4 is beta-prime cadmium gold structured and crystallizes in the tetragonal P4/n space group. The structure is zero-dimensional and consists of two [pcl4]+1 molecules and two SbF6 clusters. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There is five shorter (1.92 Å) and one longer (1.93 Å) Sb–F bond length. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.

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36 MATERIALS SCIENCECl-F-P-Sbcrystal structureSbP(Cl2F3)2

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2020-07-23. Materials Data on SbP(Cl2F3)2 by Materials Project. https://doi.org/10.17188/1270793

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