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DOE OSTI · 1271206

Materials Data on Cs(OsO3)2 by Materials Project

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Abstract

CsOs2O6 crystallizes in the cubic Fd-3m space group. The structure is three-dimensional. Cs1+ is bonded to six equivalent O2- atoms to form CsO6 octahedra that share corners with twelve equivalent OsO6 octahedra. The corner-sharing octahedral tilt angles are 70°. All Cs–O bond lengths are 3.20 Å. Os+5.50+ is bonded to six equivalent O2- atoms to form OsO6 octahedra that share corners with six equivalent CsO6 octahedra and corners with six equivalent OsO6 octahedra. The corner-sharing octahedra tilt angles range from 40–70°. All Os–O bond lengths are 1.93 Å. O2- is bonded in a distorted bent 150 degrees geometry to one Cs1+ and two equivalent Os+5.50+ atoms.

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36 MATERIALS SCIENCEcrystal structureCs(OsO3)2Cs-O-Os

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2020-04-29. Materials Data on Cs(OsO3)2 by Materials Project. https://doi.org/10.17188/1271206

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