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DOE OSTI · 1271424

Materials Data on SbCl(OF3)2 by Materials Project

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Abstract

SbF6ClO2 is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hypochlorous acid;hydrate molecules and two SbF6 clusters. In each SbF6 cluster, Sb is bonded in an octahedral geometry to six F atoms. There is four shorter (1.91 Å) and two longer (1.95 Å) Sb–F bond length. There are three inequivalent F sites. In the first F site, F is bonded in a single-bond geometry to one Sb atom. In the second F site, F is bonded in a single-bond geometry to one Sb atom. In the third F site, F is bonded in a single-bond geometry to one Sb atom.

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36 MATERIALS SCIENCECl-F-O-Sbcrystal structureSbCl(OF3)2

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2020-07-14. Materials Data on SbCl(OF3)2 by Materials Project. https://doi.org/10.17188/1271424

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