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DOE OSTI · 1272028

Materials Data on NaClO4 by Materials Project

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Abstract

NaClO4 crystallizes in the orthorhombic Pnma space group. The structure is three-dimensional. Na is bonded in a 6-coordinate geometry to six O atoms. There are a spread of Na–O bond distances ranging from 2.57–2.71 Å. There are three inequivalent O sites. In the first O site, O is bonded in a distorted linear geometry to one Na and one Cl atom. The O–Cl bond length is 1.45 Å. In the second O site, O is bonded in a 1-coordinate geometry to two equivalent Na and one Cl atom. The O–Cl bond length is 1.47 Å. In the third O site, O is bonded in a distorted bent 120 degrees geometry to one Na and one Cl atom. The O–Cl bond length is 1.46 Å. Cl is bonded in a tetrahedral geometry to four O atoms.

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36 MATERIALS SCIENCECl-Na-Ocrystal structureNaClO4

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2020-07-18. Materials Data on NaClO4 by Materials Project. https://doi.org/10.17188/1272028

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36 MATERIALS SCIENCE↗