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DOE OSTI · 1274045

Materials Data on ZnH16C4(Br2N)2 by Materials Project

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Abstract

ZnBr4((CH3)2NH2)2 is Silicon tetrafluoride-derived structured and crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of eight dimethylazanium molecules and four ZnBr4 clusters. In each ZnBr4 cluster, Zn2+ is bonded in a tetrahedral geometry to four Br1- atoms. There are a spread of Zn–Br bond distances ranging from 2.42–2.48 Å. There are four inequivalent Br1- sites. In the first Br1- site, Br1- is bonded in a single-bond geometry to one Zn2+ atom. In the second Br1- site, Br1- is bonded in a single-bond geometry to one Zn2+ atom. In the third Br1- site, Br1- is bonded in a single-bond geometry to one Zn2+ atom. In the fourth Br1- site, Br1- is bonded in a single-bond geometry to one Zn2+ atom.

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36 MATERIALS SCIENCEBr-C-H-N-Zncrystal structureZnH16C4(Br2N)2

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2020-05-31. Materials Data on ZnH16C4(Br2N)2 by Materials Project. https://doi.org/10.17188/1274045

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