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DOE OSTI · 1274985

Materials Data on SbAsPCl13 by Materials Project

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Abstract

SbCl6AsCl3PCl4 crystallizes in the orthorhombic Cmc2_1 space group. The structure is zero-dimensional and consists of four [pcl4]+1 molecules, four trichloroarsine molecules, and four SbCl6 clusters. In each SbCl6 cluster, Sb3+ is bonded in an octahedral geometry to six Cl1- atoms. There are a spread of Sb–Cl bond distances ranging from 2.41–2.43 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Sb3+ atom.

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36 MATERIALS SCIENCEAs-Cl-P-Sbcrystal structureSbAsPCl13

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2020-07-15. Materials Data on SbAsPCl13 by Materials Project. https://doi.org/10.17188/1274985

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36 MATERIALS SCIENCE↗