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DOE OSTI · 1276267

Materials Data on K2SnCl6 by Materials Project

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Abstract

K2SnCl6 crystallizes in the monoclinic P2_1/c space group. The structure is three-dimensional. K1+ is bonded in a 10-coordinate geometry to eight Cl1- atoms. There are a spread of K–Cl bond distances ranging from 3.30–3.59 Å. Sn4+ is bonded in an octahedral geometry to six Cl1- atoms. All Sn–Cl bond lengths are 2.47 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a 4-coordinate geometry to three equivalent K1+ and one Sn4+ atom. In the second Cl1- site, Cl1- is bonded in a 4-coordinate geometry to three equivalent K1+ and one Sn4+ atom. In the third Cl1- site, Cl1- is bonded in a 1-coordinate geometry to two equivalent K1+ and one Sn4+ atom.

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36 MATERIALS SCIENCECl-K-Sncrystal structureK2SnCl6

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2020-07-15. Materials Data on K2SnCl6 by Materials Project. https://doi.org/10.17188/1276267

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36 MATERIALS SCIENCE↗