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DOE OSTI · 1276375

Materials Data on Rb2MnCl6 by Materials Project

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Abstract

Rb2MnCl6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent Cl1- atoms to form RbCl12 cuboctahedra that share corners with twelve equivalent RbCl12 cuboctahedra, faces with six equivalent RbCl12 cuboctahedra, and faces with four equivalent MnCl6 octahedra. All Rb–Cl bond lengths are 3.60 Å. Mn4+ is bonded to six equivalent Cl1- atoms to form MnCl6 octahedra that share faces with eight equivalent RbCl12 cuboctahedra. All Mn–Cl bond lengths are 2.29 Å. Cl1- is bonded in a distorted single-bond geometry to four equivalent Rb1+ and one Mn4+ atom.

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36 MATERIALS SCIENCECl-Mn-Rbcrystal structureRb2MnCl6

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2020-07-15. Materials Data on Rb2MnCl6 by Materials Project. https://doi.org/10.17188/1276375

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36 MATERIALS SCIENCE↗