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DOE OSTI · 1276409

Materials Data on SbBr(OF3)2 by Materials Project

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Abstract

SbF6O2Br is beta-prime cadmium gold structured and crystallizes in the monoclinic P2/c space group. The structure is zero-dimensional and consists of two hypobromous acid;hydrate molecules and two SbF6 clusters. In each SbF6 cluster, Sb5+ is bonded in an octahedral geometry to six F1- atoms. There are a spread of Sb–F bond distances ranging from 1.90–1.95 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one Sb5+ atom.

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36 MATERIALS SCIENCEBr-F-O-Sbcrystal structureSbBr(OF3)2

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2020-07-15. Materials Data on SbBr(OF3)2 by Materials Project. https://doi.org/10.17188/1276409

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