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DOE OSTI · 1277201

Materials Data on NaSbF6 by Materials Project

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Abstract

NaSbF6 is High-temperature superconductor-derived structured and crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Na1+ is bonded to six equivalent F1- atoms to form NaF6 octahedra that share corners with six equivalent SbF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Na–F bond lengths are 2.32 Å. Sb5+ is bonded to six equivalent F1- atoms to form SbF6 octahedra that share corners with six equivalent NaF6 octahedra. The corner-sharing octahedral tilt angles are 0°. All Sb–F bond lengths are 1.92 Å. F1- is bonded in a linear geometry to one Na1+ and one Sb5+ atom.

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36 MATERIALS SCIENCEcrystal structureF-Na-SbNaSbF6

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2020-07-14. Materials Data on NaSbF6 by Materials Project. https://doi.org/10.17188/1277201

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