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DOE OSTI · 1277530

Materials Data on AgCNO by Materials Project

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Abstract

AgNCO crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Ag1+ is bonded to two equivalent C4+ and four equivalent O2- atoms to form a mixture of distorted face, edge, and corner-sharing AgC2O4 octahedra. The corner-sharing octahedral tilt angles are 57°. Both Ag–C bond lengths are 2.14 Å. All Ag–O bond lengths are 3.08 Å. C4+ is bonded in a 3-coordinate geometry to two equivalent Ag1+ and one N3- atom. The C–N bond length is 1.19 Å. N3- is bonded in a linear geometry to one C4+ and one O2- atom. The N–O bond length is 1.23 Å. O2- is bonded in a distorted single-bond geometry to four equivalent Ag1+ and one N3- atom.

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36 MATERIALS SCIENCEAg-C-N-OAgCNOcrystal structure

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2020-07-16. Materials Data on AgCNO by Materials Project. https://doi.org/10.17188/1277530

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