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DOE OSTI · 1277859

Materials Data on C2SN2 by Materials Project

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Abstract

S(CN)2 crystallizes in the orthorhombic Pbca space group. The structure is zero-dimensional and consists of eight sulfur dicyanide molecules. there are two inequivalent C4+ sites. In the first C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.17 Å. The C–S bond length is 1.70 Å. In the second C4+ site, C4+ is bonded in a distorted linear geometry to one N3- and one S2- atom. The C–N bond length is 1.17 Å. The C–S bond length is 1.70 Å. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a single-bond geometry to one C4+ atom. In the second N3- site, N3- is bonded in a single-bond geometry to one C4+ atom. S2- is bonded in a 2-coordinate geometry to two C4+ atoms.

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36 MATERIALS SCIENCEC-N-SC2SN2crystal structure

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2020-04-30. Materials Data on C2SN2 by Materials Project. https://doi.org/10.17188/1277859

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