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DOE OSTI · 1278320

Materials Data on H3ClO5 by Materials Project

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Abstract

H3OClO4 is Modderite-like structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of four hydrogen hydrate molecules and four ClO4 clusters. In each ClO4 cluster, there are three inequivalent O sites. In the first O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.47 Å. In the second O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.48 Å. In the third O site, O is bonded in a single-bond geometry to one Cl atom. The O–Cl bond length is 1.44 Å. Cl is bonded in a tetrahedral geometry to four O atoms.

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36 MATERIALS SCIENCECl-H-Ocrystal structureH3ClO5

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2020-04-30. Materials Data on H3ClO5 by Materials Project. https://doi.org/10.17188/1278320

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