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DOE OSTI · 1278916

Materials Data on Rb2PdI6 by Materials Project

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Abstract

Rb2PdI6 crystallizes in the cubic Fm-3m space group. The structure is three-dimensional. Rb1+ is bonded to twelve equivalent I1- atoms to form RbI12 cuboctahedra that share corners with twelve equivalent RbI12 cuboctahedra, faces with six equivalent RbI12 cuboctahedra, and faces with four equivalent PdI6 octahedra. All Rb–I bond lengths are 4.05 Å. Pd4+ is bonded to six equivalent I1- atoms to form PdI6 octahedra that share faces with eight equivalent RbI12 cuboctahedra. All Pd–I bond lengths are 2.73 Å. I1- is bonded to four equivalent Rb1+ and one Pd4+ atom to form a mixture of distorted face, edge, and corner-sharing IRb4Pd square pyramids.

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36 MATERIALS SCIENCEcrystal structureI-Pd-RbRb2PdI6

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2020-07-15. Materials Data on Rb2PdI6 by Materials Project. https://doi.org/10.17188/1278916

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