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DOE OSTI · 1280301

Materials Data on CuH4Pb2(ClO2)2 by Materials Project

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Abstract

Pb2Cu(OH)4Cl2 crystallizes in the tetragonal P4mm space group. The structure is two-dimensional and consists of one hydrochloric acid molecule and one CuPb2H4O4Cl sheet oriented in the (0, 0, 1) direction. In the CuPb2H4O4Cl sheet, Cu2+ is bonded in a 4-coordinate geometry to four equivalent O2- and one Cl1- atom. All Cu–O bond lengths are 2.00 Å. The Cu–Cl bond length is 2.58 Å. Pb2+ is bonded in a 4-coordinate geometry to four equivalent O2- atoms. All Pb–O bond lengths are 2.50 Å. H1+ is bonded in a single-bond geometry to one O2- atom. The H–O bond length is 0.99 Å. O2- is bonded in a 1-coordinate geometry to one Cu2+, two equivalent Pb2+, and one H1+ atom. Cl1- is bonded in a 1-coordinate geometry to one Cu2+ atom.

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36 MATERIALS SCIENCECl-Cu-H-O-Pbcrystal structureCuH4Pb2(ClO2)2

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2020-07-16. Materials Data on CuH4Pb2(ClO2)2 by Materials Project. https://doi.org/10.17188/1280301

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