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DOE OSTI · 1281499

Materials Data on SeCl4 by Materials Project

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Abstract

SeCl4 crystallizes in the cubic P-43n space group. The structure is zero-dimensional and consists of eight SeCl4 clusters. Se4+ is bonded to six Cl1- atoms to form distorted edge-sharing SeCl6 octahedra. There are a spread of Se–Cl bond distances ranging from 2.20–2.92 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Se4+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Se4+ atom. In the third Cl1- site, Cl1- is bonded in a 3-coordinate geometry to three equivalent Se4+ atoms. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one Se4+ atom.

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36 MATERIALS SCIENCECl-Secrystal structureSeCl4

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2014-06-04. Materials Data on SeCl4 by Materials Project. https://doi.org/10.17188/1281499

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