Materials Data on Pu5Pt3 by Materials Project

Abstract

Pu5Pt3 crystallizes in the monoclinic C2 space group. The structure is three-dimensional. there are seven inequivalent Pu sites. In the first Pu site, Pu is bonded in a 5-coordinate geometry to five Pt atoms. There are a spread of Pu–Pt bond distances ranging from 2.92–3.24 Å. In the second Pu site, Pu is bonded in a 5-coordinate geometry to five Pt atoms. There are a spread of Pu–Pt bond distances ranging from 2.90–3.24 Å. In the third Pu site, Pu is bonded in a 6-coordinate geometry to six Pt atoms. There are two shorter (3.02 Å) and four longer (3.03 Å) Pu–Pt bond lengths. In the fourth Pu site, Pu is bonded in a 5-coordinate geometry to five Pt atoms. There are a spread of Pu–Pt bond distances ranging from 2.91–3.24 Å. In the fifth Pu site, Pu is bonded in a 6-coordinate geometry to six Pt atoms. All Pu–Pt bond lengths are 3.04 Å. In the sixth Pu site, Pu is bonded in a 6-coordinate geometry to six Pt atoms. There are two shorter (3.02 Å) and four longer (3.03 Å) Pu–Pt bond lengths. In the seventh Pu site, Pu is bonded in a 6-coordinate geometry to six Pt atoms. There are four shorter (3.03 Å) and two longer (3.04 Å) Pu–Pt bond lengths. There are three inequivalent Pt sites. In the first Pt site, Pt is bonded in a 9-coordinate geometry to nine Pu atoms. In the second Pt site, Pt is bonded in a 9-coordinate geometry to nine Pu atoms. In the third Pt site, Pt is bonded in a 9-coordinate geometry to nine Pu atoms.