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DOE OSTI · 1285017

Materials Data on MnH8(N2Cl)2 by Materials Project

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Abstract

MnH8(N2Cl)2 crystallizes in the monoclinic C2/m space group. The structure is zero-dimensional and consists of two MnH8(N2Cl)2 clusters. Mn2+ is bonded in an octahedral geometry to four equivalent N2- and two equivalent Cl1- atoms. All Mn–N bond lengths are 2.30 Å. Both Mn–Cl bond lengths are 2.57 Å. N2- is bonded in a distorted water-like geometry to one Mn2+ and two H1+ atoms. Both N–H bond lengths are 1.03 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one N2- atom. Cl1- is bonded in a single-bond geometry to one Mn2+ atom.

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36 MATERIALS SCIENCECl-H-Mn-Ncrystal structureMnH8(N2Cl)2

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2020-07-16. Materials Data on MnH8(N2Cl)2 by Materials Project. https://doi.org/10.17188/1285017

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