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DOE OSTI · 1287856

Materials Data on HgH16C6(N2Cl)2 by Materials Project

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Abstract

HgC2(NCl)2(CH3)2(CH3NH2)2 crystallizes in the monoclinic C2/c space group. The structure is zero-dimensional and consists of eight methane molecules, eight methylammonium molecules, and four HgC2(NCl)2 clusters. In each HgC2(NCl)2 cluster, Hg2+ is bonded in a 4-coordinate geometry to two equivalent C+0.67- and two equivalent Cl1- atoms. Both Hg–C bond lengths are 2.06 Å. Both Hg–Cl bond lengths are 2.95 Å. C+0.67- is bonded in a distorted linear geometry to one Hg2+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a single-bond geometry to one C+0.67- atom. Cl1- is bonded in a 2-coordinate geometry to one Hg2+ atom.

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36 MATERIALS SCIENCEC-Cl-H-Hg-Ncrystal structureHgH16C6(N2Cl)2

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2020-04-29. Materials Data on HgH16C6(N2Cl)2 by Materials Project. https://doi.org/10.17188/1287856

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