Materials Data on LiAgF3 by Materials Project

Abstract

LiAgF3 crystallizes in the triclinic P-1 space group. The structure is three-dimensional. Li1+ is bonded in a distorted bent 120 degrees geometry to three F1- atoms. There are a spread of Li–F bond distances ranging from 1.29–2.63 Å. Ag2+ is bonded in a 6-coordinate geometry to six F1- atoms. There are a spread of Ag–F bond distances ranging from 1.96–2.84 Å. There are three inequivalent F1- sites. In the first F1- site, F1- is bonded in a 1-coordinate geometry to one Li1+ and two equivalent Ag2+ atoms. In the second F1- site, F1- is bonded in a distorted single-bond geometry to one Li1+ and two equivalent Ag2+ atoms. In the third F1- site, F1- is bonded in a distorted single-bond geometry to one Li1+ and two equivalent Ag2+ atoms.