Materials Data on Sb3H18C6N by Materials Project

Abstract

C6Sb3NH18 crystallizes in the monoclinic P2_1/c space group. The structure is zero-dimensional and consists of four [[bis(dimethylstibanyl)amino]-methylstibanyl]methane molecules. there are six inequivalent C1- sites. In the first C1- site, C1- is bonded in a distorted trigonal non-coplanar geometry to one Sb3- and three H1+ atoms. The C–Sb bond length is 2.19 Å. All C–H bond lengths are 1.10 Å. In the second C1- site, C1- is bonded in a distorted trigonal non-coplanar geometry to one Sb3- and three H1+ atoms. The C–Sb bond length is 2.19 Å. All C–H bond lengths are 1.10 Å. In the third C1- site, C1- is bonded in a distorted trigonal non-coplanar geometry to one Sb3- and three H1+ atoms. The C–Sb bond length is 2.19 Å. All C–H bond lengths are 1.10 Å. In the fourth C1- site, C1- is bonded in a distorted trigonal non-coplanar geometry to one Sb3- and three H1+ atoms. The C–Sb bond length is 2.19 Å. There is one shorter (1.09 Å) and two longer (1.10 Å) C–H bond length. In the fifth C1- site, C1- is bonded in a distorted trigonal non-coplanar geometry to one Sb3- and three H1+ atoms. The C–Sb bond length is 2.19 Å. All C–H bond lengths are 1.10 Å. In the sixth C1- site, C1- is bonded in a distorted trigonal non-coplanar geometry to one Sb3- and three H1+ atoms. The C–Sb bond length is 2.18 Å. All C–H bond lengths are 1.10 Å. There are three inequivalent Sb3- sites. In the first Sb3- site, Sb3- is bonded in a distorted T-shaped geometry to two C1- and one N3- atom. The Sb–N bond length is 2.08 Å. In the second Sb3- site, Sb3- is bonded in a 3-coordinate geometry to two C1- and one N3- atom. The Sb–N bond length is 2.08 Å. In the third Sb3- site, Sb3- is bonded in a 3-coordinate geometry to two C1- and one N3- atom. The Sb–N bond length is 2.08 Å. N3- is bonded in a trigonal planar geometry to three Sb3- atoms. There are seventeen inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the fourth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the fifth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the sixth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the seventh H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the eighth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the ninth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the tenth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the eleventh H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the twelfth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the thirteenth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the fourteenth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the fifteenth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the sixteenth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom. In the seventeenth H1+ site, H1+ is bonded in a single-bond geometry to one C1- atom.