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DOE OSTI · 1292562

Materials Data on ZnH12N4Cl4O3 by Materials Project

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Abstract

ZnCl4(NH4)3NO3 is Silicon tetrafluoride-derived structured and crystallizes in the orthorhombic Pnma space group. The structure is zero-dimensional and consists of twelve ammonium molecules, four nitric acid molecules, and four ZnCl4 clusters. In each ZnCl4 cluster, Zn2+ is bonded in a tetrahedral geometry to four Cl1- atoms. There are a spread of Zn–Cl bond distances ranging from 2.26–2.36 Å. There are three inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one Zn2+ atom.

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36 MATERIALS SCIENCECl-H-N-O-Zncrystal structureZnH12N4Cl4O3

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2020-06-01. Materials Data on ZnH12N4Cl4O3 by Materials Project. https://doi.org/10.17188/1292562

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DOE OSTI2026

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