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DOE OSTI · 1293157

Materials Data on LiV(CO3)2 by Materials Project

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Abstract

LiV(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R32 space group. The structure is three-dimensional. Li1+ is bonded to six equivalent O2- atoms to form distorted LiO6 pentagonal pyramids that share corners with six equivalent VO6 pentagonal pyramids. All Li–O bond lengths are 2.29 Å. V3+ is bonded to six equivalent O2- atoms to form distorted VO6 pentagonal pyramids that share corners with six equivalent LiO6 pentagonal pyramids. All V–O bond lengths are 2.07 Å. C4+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. All C–O bond lengths are 1.30 Å. O2- is bonded in a distorted trigonal planar geometry to one Li1+, one V3+, and one C4+ atom.

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36 MATERIALS SCIENCEC-Li-O-Vcrystal structureLiV(CO3)2

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2020-05-03. Materials Data on LiV(CO3)2 by Materials Project. https://doi.org/10.17188/1293157

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36 MATERIALS SCIENCE↗