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DOE OSTI · 1298893

Materials Data on LiMn(CO3)2 by Materials Project

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Abstract

LiMn(CO3)2 is Calcite-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Li1+ is bonded to six equivalent O2- atoms to form LiO6 octahedra that share corners with six equivalent MnO6 octahedra. The corner-sharing octahedral tilt angles are 59°. All Li–O bond lengths are 2.22 Å. Mn3+ is bonded to six equivalent O2- atoms to form MnO6 octahedra that share corners with six equivalent LiO6 octahedra. The corner-sharing octahedral tilt angles are 59°. All Mn–O bond lengths are 2.10 Å. C4+ is bonded in a trigonal planar geometry to three equivalent O2- atoms. All C–O bond lengths are 1.29 Å. O2- is bonded in a trigonal planar geometry to one Li1+, one Mn3+, and one C4+ atom.

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36 MATERIALS SCIENCEC-Li-Mn-Ocrystal structureLiMn(CO3)2

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2020-08-03. Materials Data on LiMn(CO3)2 by Materials Project. https://doi.org/10.17188/1298893

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36 MATERIALS SCIENCE↗