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DOE OSTI · 1309150

Materials Data on PdPtF6 by Materials Project

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Abstract

PtPdF6 is Upper Bainite-derived structured and crystallizes in the trigonal R-3 space group. The structure is three-dimensional. Pt4+ is bonded to six equivalent F1- atoms to form PtF6 octahedra that share corners with six equivalent PdF6 octahedra. The corner-sharing octahedral tilt angles are 45°. All Pt–F bond lengths are 1.98 Å. Pd2+ is bonded to six equivalent F1- atoms to form PdF6 octahedra that share corners with six equivalent PtF6 octahedra. The corner-sharing octahedral tilt angles are 45°. All Pd–F bond lengths are 2.18 Å. F1- is bonded in a distorted bent 120 degrees geometry to one Pt4+ and one Pd2+ atom.

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36 MATERIALS SCIENCEcrystal structureF-Pd-PtPdPtF6

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2020-07-17. Materials Data on PdPtF6 by Materials Project. https://doi.org/10.17188/1309150

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