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DOE OSTI · 1310790

Materials Data on VCl4 by Materials Project

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Abstract

VCl4 crystallizes in the monoclinic P2 space group. The structure is zero-dimensional and consists of two VCl4 clusters. V4+ is bonded to five Cl1- atoms to form distorted edge-sharing VCl5 trigonal bipyramids. There are a spread of V–Cl bond distances ranging from 2.13–2.56 Å. There are four inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in an L-shaped geometry to two equivalent V4+ atoms. In the second Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom. In the third Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom. In the fourth Cl1- site, Cl1- is bonded in a single-bond geometry to one V4+ atom.

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36 MATERIALS SCIENCECl-Vcrystal structureVCl4

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2017-07-21. Materials Data on VCl4 by Materials Project. https://doi.org/10.17188/1310790

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36 MATERIALS SCIENCE↗