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DOE OSTI · 1316035

Materials Data on SmGeO3 by Materials Project

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Abstract

SmGeO3 is (Cubic) Perovskite structured and crystallizes in the cubic Pm-3m space group. The structure is three-dimensional. Sm2+ is bonded to twelve equivalent O2- atoms to form SmO12 cuboctahedra that share corners with twelve equivalent SmO12 cuboctahedra, faces with six equivalent SmO12 cuboctahedra, and faces with eight equivalent GeO6 octahedra. All Sm–O bond lengths are 2.79 Å. Ge4+ is bonded to six equivalent O2- atoms to form GeO6 octahedra that share corners with six equivalent GeO6 octahedra and faces with eight equivalent SmO12 cuboctahedra. The corner-sharing octahedral tilt angles are 0°. All Ge–O bond lengths are 1.97 Å. O2- is bonded in a distorted linear geometry to four equivalent Sm2+ and two equivalent Ge4+ atoms.

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36 MATERIALS SCIENCEcrystal structureGe-O-SmSmGeO3

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2020-07-23. Materials Data on SmGeO3 by Materials Project. https://doi.org/10.17188/1316035

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