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DOE OSTI · 1316515

Materials Data on SnH22C6(NCl2)2 by Materials Project

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Abstract

((CH3)2NH2)2SnH6(CCl2)2 crystallizes in the triclinic P-1 space group. The structure is zero-dimensional and consists of two dimethylazanium molecules and one SnH6(CCl2)2 cluster. In the SnH6(CCl2)2 cluster, Sn4+ is bonded in an octahedral geometry to two equivalent C+2.67- and four Cl1- atoms. Both Sn–C bond lengths are 2.15 Å. There are two shorter (2.66 Å) and two longer (2.68 Å) Sn–Cl bond lengths. C+2.67- is bonded in a distorted trigonal non-coplanar geometry to one Sn4+ and three H1+ atoms. All C–H bond lengths are 1.09 Å. There are three inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the second H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. In the third H1+ site, H1+ is bonded in a single-bond geometry to one C+2.67- atom. There are two inequivalent Cl1- sites. In the first Cl1- site, Cl1- is bonded in a single-bond geometry to one Sn4+ atom. In the second Cl1- site, Cl1- is bonded in a distorted single-bond geometry to one Sn4+ atom.

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36 MATERIALS SCIENCEC-Cl-H-N-Sncrystal structureSnH22C6(NCl2)2

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2020-07-23. Materials Data on SnH22C6(NCl2)2 by Materials Project. https://doi.org/10.17188/1316515

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36 MATERIALS SCIENCE↗