Materials Data on AgHO2 by Materials Project

Abstract

AgHO2 crystallizes in the triclinic P1 space group. The structure is three-dimensional. there are two inequivalent Ag3+ sites. In the first Ag3+ site, Ag3+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.11–2.50 Å. In the second Ag3+ site, Ag3+ is bonded in a rectangular see-saw-like geometry to four O2- atoms. There are a spread of Ag–O bond distances ranging from 2.11–2.50 Å. There are two inequivalent H1+ sites. In the first H1+ site, H1+ is bonded in a distorted linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.61 Å) H–O bond length. In the second H1+ site, H1+ is bonded in a distorted linear geometry to two O2- atoms. There is one shorter (1.02 Å) and one longer (1.62 Å) H–O bond length. There are four inequivalent O2- sites. In the first O2- site, O2- is bonded in a distorted single-bond geometry to two Ag3+ and two H1+ atoms. In the second O2- site, O2- is bonded in a trigonal planar geometry to two Ag3+ and one O2- atom. The O–O bond length is 1.30 Å. In the third O2- site, O2- is bonded in a distorted single-bond geometry to two Ag3+ and two H1+ atoms. In the fourth O2- site, O2- is bonded in a trigonal planar geometry to two Ag3+ and one O2- atom.