Materials Data on VF4 by Materials Project

Abstract

VF4 crystallizes in the triclinic P1 space group. The structure is zero-dimensional and consists of two tetrafluorovanadium molecules. V4+ is bonded in a square co-planar geometry to four F1- atoms. There are a spread of V–F bond distances ranging from 1.79–1.81 Å. There are four inequivalent F1- sites. In the first F1- site, F1- is bonded in a single-bond geometry to one V4+ atom. In the second F1- site, F1- is bonded in a single-bond geometry to one V4+ atom. In the third F1- site, F1- is bonded in a single-bond geometry to one V4+ atom. In the fourth F1- site, F1- is bonded in a single-bond geometry to one V4+ atom.