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DOE OSTI · 1319445

Materials Data on SbN by Materials Project

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Abstract

SbN is Hittorf-derived structured and crystallizes in the triclinic P1 space group. The structure is two-dimensional and consists of one SbN sheet oriented in the (0, 0, 1) direction. there are two inequivalent Sb3+ sites. In the first Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three N3- atoms. There are one shorter (2.11 Å) and two longer (2.12 Å) Sb–N bond lengths. In the second Sb3+ site, Sb3+ is bonded in a distorted T-shaped geometry to three N3- atoms. There are one shorter (2.11 Å) and two longer (2.12 Å) Sb–N bond lengths. There are two inequivalent N3- sites. In the first N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Sb3+ atoms. In the second N3- site, N3- is bonded in a trigonal non-coplanar geometry to three Sb3+ atoms.

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36 MATERIALS SCIENCEcrystal structureN-SbSbN

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2020-07-20. Materials Data on SbN by Materials Project. https://doi.org/10.17188/1319445

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