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DOE OSTI · 1467849

Liquid interfaces with pH-switchable nanoparticle arrays

Srivastava, Sunita·Fukuto, Masafumi·Gang, Oleg
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Abstract

Stimuli-responsive 2D nanoscale systems offer intriguing opportunities for creating switchable interfaces. At liquid interfaces, such systems can provide control over interfacial energies, surface structure, and rheological and transport characteristics, which is relevant, for example, to bio- and chemical reactors, microfluidic devices, and soft robotics. We explore the formation of a pH-responsive membrane formed from gold nanoparticles grafted with DNA (DNA–NPs) at a liquid–vapor interface. A DNA–NP 2D hexagonal lattice can be reversibly switched by pH modulation between an expanded state of non-connected nanoparticles at neutral pH and a contracted state of linked nanoparticles at acidic pH due to the AH + –H + A base pairing between A-motifs. Our in situ surface X-ray scattering studies reveal that the reversible lattice contraction can be tuned by the length of pH-activated linkers, with up to ~71% change in surface area.

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59 BASIC BIOLOGICAL SCIENCES77 NANOSCIENCE AND NANOTECHNOLOGYDNALiquid interfacesNanoparticlesResponsive nanostructuresSelf-assembly

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Srivastava, Sunita, Fukuto, Masafumi, Gang, Oleg. 2018-04-16. Liquid interfaces with pH-switchable nanoparticle arrays. https://doi.org/10.1039/c8sm00583d

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