DOE OSTI · 1576825
Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing
Abstract
The rhenium( i ) salt Na[Re(η 5 -Cp)(BDI)] can be cooled in solution under a dinitrogen atmosphere to selectively access complexes containing rhenium( iii ) centers bound to direduced, doubly-bonded N 2 ( i.e. diazenide) fragments.
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Lohrey, Trevor D., Bergman, Robert G., Arnold, John. 2019-12-10. Controlling dinitrogen functionalization at rhenium through alkali metal ion pairing. https://doi.org/10.1039/c9dt04489b
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