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DOE OSTI · 1605046

Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids [plus supplemental information]

Kelley, Steven P.·Smetana, Volodymyr·Emerson, Stephen D.·Mudring, Anja-Verena·Rogers, Robin D.
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Abstract

By dehydrating actinide salts with an ionic liquid containing a common anion and subsequent reaction with N-heterocyclic ligands, we challenge the concept that actinides prefer O- over N-donors; rather the acidic hydrogen atoms of protic solvents hinder the formation of more elusive f-element N-donor coordination complexes.

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Kelley, Steven P., Smetana, Volodymyr, Emerson, Stephen D., Mudring, Anja-Verena, Rogers, Robin D.. 2020-03-10. Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids [plus supplemental information]. https://doi.org/10.1039/c9cc09852f

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