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DOE OSTI · 1651049

Methods for liquid extraction of rare earth metals using ionic liquids

Freiderich, John William·Luo, Huimin·Moyer, Bruce A.·Dai, Sheng
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Abstract

A method for extracting a rare earth element from a rare earth-containing substance, the method comprising mixing the rare earth-containing substance with a protic ionic liquid, such as: wherein R1 is selected from hydrogen atom and hydrocarbon groups containing 1 to 6 carbon atoms; R2 and R3 are independently selected from hydrocarbon groups containing 1 to 12 carbon atoms; and X− is an anionic species; to produce a composition of the formula (RE)(amide)yXz at least partially dissolved in the protic ionic liquid, wherein RE is at least one rare earth element having an atomic number selected from 39, 57-71, and 90-103; y is 2-6; z is a number that charge balances the total positive charge of RE; and the amide is the conjugate base of the cationic portion of the protic ionic liquid of Formula (1) and has the following formula:

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Freiderich, John William, Luo, Huimin, Moyer, Bruce A., Dai, Sheng. 2020-06-23. Methods for liquid extraction of rare earth metals using ionic liquids. https://www.osti.gov/biblio/1651049

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