Materials Data on RbHgC2N2ClO by Materials Project

Abstract

RbHgC2N2OCl crystallizes in the orthorhombic Cmcm space group. The structure is three-dimensional. Rb1+ is bonded in a 6-coordinate geometry to two equivalent N3-, two equivalent O2-, and two equivalent Cl1- atoms. Both Rb–N bond lengths are 2.96 Å. Both Rb–O bond lengths are 3.07 Å. Both Rb–Cl bond lengths are 3.94 Å. Hg2+ is bonded in a distorted square co-planar geometry to two equivalent C3+ and two equivalent Cl1- atoms. Both Hg–C bond lengths are 2.05 Å. Both Hg–Cl bond lengths are 2.91 Å. C3+ is bonded in a linear geometry to one Hg2+ and one N3- atom. The C–N bond length is 1.17 Å. N3- is bonded in a 1-coordinate geometry to one Rb1+ and one C3+ atom. O2- is bonded in a water-like geometry to two equivalent Rb1+ atoms. Cl1- is bonded in a 4-coordinate geometry to two equivalent Rb1+ and two equivalent Hg2+ atoms.