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DOE OSTI · 1661599

A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction

Anderson, Christopher L.·Liang, Jiatao·Teat, Simon J.·Garzón-Ruiz, Andrés·Nenon, David P.·Navarro, Amparo·Liu, Yi
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Abstract

Here the generation of a highly-substituted [2.2](2,5)pyrazinophane via a cascade reaction is presented. The pyrazinophane product is formed via the dimerization of a member of the para-azaquinodimethane (p-AQM) family of conjugated quinoidal compounds—reactivity that sheds light on the nature of stability in p-AQMs. Additionally, the electronic and structural nature of this highly-strained ring system are characterized.

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Anderson, Christopher L., Liang, Jiatao, Teat, Simon J., Garzón-Ruiz, Andrés, Nenon, David P., Navarro, Amparo, Liu, Yi. 2020-03-10. A highly substituted pyrazinophane generated from a quinoidal system via a cascade reaction. https://doi.org/10.1039/d0cc00916d

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