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DOE OSTI · 1664920

Materials Data on Cs2Pu(Cl2O)2 by Materials Project

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Abstract

Cs2Pu(OCl2)2 crystallizes in the monoclinic C2/m space group. The structure is three-dimensional. Cs1+ is bonded in a 9-coordinate geometry to one O2- and eight equivalent Cl1- atoms. The Cs–O bond length is 3.74 Å. There are a spread of Cs–Cl bond distances ranging from 3.63–3.75 Å. Pu6+ is bonded in a distorted linear geometry to two equivalent O2- and four equivalent Cl1- atoms. Both Pu–O bond lengths are 1.78 Å. All Pu–Cl bond lengths are 2.67 Å. O2- is bonded in a single-bond geometry to one Cs1+ and one Pu6+ atom. Cl1- is bonded in a 1-coordinate geometry to four equivalent Cs1+ and one Pu6+ atom.

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36 MATERIALS SCIENCECl-Cs-O-Pucrystal structureCs2Pu(Cl2O)2

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2020-07-16. Materials Data on Cs2Pu(Cl2O)2 by Materials Project. https://doi.org/10.17188/1664920

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36 MATERIALS SCIENCE↗