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DOE OSTI · 1666718

Materials Data on Nd(CoP3)4 by Materials Project

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Abstract

Nd(CoP3)4 crystallizes in the cubic Im-3 space group. The structure is three-dimensional. Nd3+ is bonded to twelve equivalent P1- atoms to form NdP12 cuboctahedra that share faces with eight equivalent CoP6 octahedra. All Nd–P bond lengths are 2.99 Å. Co+2.25+ is bonded to six equivalent P1- atoms to form CoP6 octahedra that share corners with six equivalent CoP6 octahedra and faces with two equivalent NdP12 cuboctahedra. The corner-sharing octahedral tilt angles are 60°. All Co–P bond lengths are 2.26 Å. P1- is bonded in a 2-coordinate geometry to one Nd3+, two equivalent Co+2.25+, and two equivalent P1- atoms. Both P–P bond lengths are 2.30 Å.

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36 MATERIALS SCIENCECo-Nd-Pcrystal structureNd(CoP3)4

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2020-07-14. Materials Data on Nd(CoP3)4 by Materials Project. https://doi.org/10.17188/1666718

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